SECTION 1:     CHEMICAL AND MANUFACTURER IDENTIFICATION
Product Name: BrilloDuro Triple-9 Top Coat B    Product Code: 0365F201

Manufactured For:
Action Industrial Coatings, LLC
3463 N. Gillett St
Appleton, WI 54914
(920) 470-0838

24 Hour Emergency:  INFOTRAC: 1-800-535-5053

Outside U.S. and Canada:  Infotrac: 352-323-3500

INFOTRAC Customer ID: 72826

NOTE: INFOTRAC and National Response Center 
emergency numbers to be used only in the event 
of chemical emergencies involving a spill, leak, fire, 
exposure or accident involving chemicals
Not recommended for: 
Because many of the conditions are within the user's knowledge and control, it is essential that the user evaluate and determine whether the product is suitable and appropriate for a particular use and intended application, and complies with all local applicable laws, regulations, standards, and guidance.
SECTION 2:     HAZARD(S) IDENTIFICATION

Prepared according to Global Harmonized System (GHS) Standards

GHS Classification Scale                 1=Severe Hazard; 4=Slight Hazard

GHS Ratings:
Flammable liquid
2
Flash point < 23°C and initial boiling point > 35°C (95°F)
Inhalation Toxicity
4
Gases>2500+<=20000ppm, Vapors>10+<=20mg/l, Dusts&mists>1+<=5mg/l
Eye corrosive
2A
Eye irritant: Subcategory 2A, Reversible in 21 days
Respiratory sensitizer
1
Respiratory sensitizer
Skin sensitizer
1
Skin sensitizer
Organ toxin single exposure
3
Transient target organ effects- Narcotic effects- Respiratory tract irritation
GHS Hazards
H225
Highly flammable liquid and vapour
H317
May cause an allergic skin reaction
H319
Causes serious eye irritation
H332
Harmful if inhaled
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335
May cause respiratory irritation
H336
May cause drowsiness or dizziness
SDS for:  0365F201
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GHS Precautions
P210
Keep away from heat, sparks, open flames and hot surfaces. No smoking!
P233
Keep container tightly closed
P240
Ground / bond container and receiving equipment
P241
Use explosion-proof electrical, ventilating, lighting equipment
P242
Use only non-sparking tools
P243
Take precautionary measures against static discharge
P261
Avoid breathing dust/fume/gas/mist/vapours/spray
P264
Wash thoroughly after handling
P271
Use only outdoors or in a well-ventilated area
P272
Contaminated work clothing should not be allowed out of the workplace
P280
Wear protective gloves, protective clothing, eye protection, face protection
P285
In case of inadequate ventilation wear respiratory protection
P312
Call a POISON CENTER or doctor/physician if you feel unwell
P321
Specific treatment (see first aid section on this label/SDS)
P363
Wash contaminated clothing before reuse
P302+P352
IF ON SKIN: Wash with soap and water
P303+P361+P353
IF ON SKIN (or hair): Remove / Take off all contaminated clothing immediately. Rinse skin thoroughly with water / shower
P304+P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P304+P341
IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing
P305+P351+P338
IF IN EYES: Rinse continuously with cool water for at least 15 minutes.  Remove contact lenses if present and easy to do. Continue rinsing.
P333+P313
If skin irritation or a rash occurs: Get medical advice/attention
P337+P313
If eye irritation persists get medical advice / attention
P342+P311
Call a POISON CENTER or doctor/physician
P370+P378
In case of fire: Use dry chemical / CO2 / foam for extinction
P405
Store locked up
P403+P233
Store in a well ventilated area. Keep container tightly closed.
P403+P235
Store in a well ventilated area. Keep cool
P501
Dispose of contents / container to an approved waste disposal facility
Signal Word: Danger
SECTION 3:     COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name 
CAS number
Weight Concentration %
Hexamethylene diisocyanate homopolymer
28182-81-2
70.00% - 80.00%
n-Butyl acetate
123-86-4
10.00% - 20.00%
Acetone
67-64-1
10.00% - 20.00%
Hexamethylene diisocyanate
822-06-0
0.00% - 0.10%
SECTION 4:     FIRST AID MEASURES

Inhalation:  Move affected person to fresh air. If breathing has stopped, administer CPR. If the person vomits, clean 
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the airway and turn their head to the side to prevent choking. If the person is unconscious but breathing, place them stably on their left side in the recovery position. Never give anything by mouth to an unconscious person. Seek immediate medical attention.

Eyes:  Flush eyes gently with clean water for at least 15 minutes. If irritation persists, seek immediate medical attention.

Skin:  Remove any contaminated clothing using appropriate gloves. Rinse skin thoroughly for 15 minutes in a shower or with a hose. Seek immediate medical attention.

Ingestion:  Rinse mouth with water to remove any residual chemical. If the person vomits, clean their airway and turn their head to the side to prevent choking. DO NOT induce vomiting and DO NOT give them anything to drink unless directed to do so by a physician. If the person is unconscious but breathing, place them stably on their left side in recovery position. Never give anything by mouth to an unconscious person. Seek immediate medical attention.

Additional Notes to Physician - Treat symptomatically. No specific antidote available
SECTION 5:     FIREFIGHTING MEASURES
Flash Point:   -20 C (-4 F)
LEL: 1.0%
UEL: N/A

Suitable Extinguishing Media:  
Foam
Carbon Dioxide (CO2)
Dry Chemical
Specific Hazards During Firefighting:  Prevent firefighting run-off from entering drains or sewers.

Byproducts of Combustion:  Fires involving this product may release oxides of carbon and nitrogen, reactive hydrocarbons, and irritating vapors.

Unusual Fire and Explosion Hazards:  Any closed container may rupture when exposed to extreme heat. Use a water spray to cool sealed containers. Solvent vapors are heavier than air and can travel along the ground. 

SECTION 6:     ACCIDENTAL RELEASE MEASURES

Spill / Leak Clean-Up Procedures:
 
Immediately turn off or isolate any source of ignition (pilot lights, electrical equipment, flames, heaters, etc.). Evacuate area and ventilate. Personnel wearing proper protective equipment should contain spill immediately with inert materials (sand, earth, chemical spill pads of cotton) by forming dikes. Dikes should be placed to contain spill in a manner that will prevent material from entering sewers and waterways. Large spills, once contained, may be picked up using explosion proof, non-sparking vacuum pumps, shovels, or buckets, and disposed of in suitable containers. If a large spill occurs notify the appropriate authorities. 

In case of road spill or accident contact INFOTRAC (1-800-535-5053).

CAUTION:  If spilled material is cleaned up using a regulated solvent, the resulting waste mixture will also be regulated.

Do not empty into drains. All disposal must comply with federal, state, and local regulations. The material, if spilled or discarded, may be a regulated waste. Refer to state and local regulations. Department of Transportation (DOT) regulations may apply for transporting this material when spilled. See Section 14.

SDS for:  0365F201
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SECTION 7:     HANDLING AND STORAGE

Handling Precautions:  

Open containers carefully and in a well ventilated area, and use appropriate respiratory protection. Wash hands thoroughly after handling. Keep containers closed when not in use. Do not transfer to unmarked containers. Empty containers contain product residue which may exhibit hazardous properties therefore, do not pressurize, cut, glaze, weld or use for any other purpose. Return drums to reclamation center for proper cleaning and reuse.

Storage Requirements:
  
Store in a cool, dry, well ventilated area. Keep containers tightly closed and store away from heat, sparks, open flame or oxidizing materials. Extended storage at excessive temperatures may produce odorous and toxic fumes from product decomposition.

SECTION 8:     EXPOSURE CONTROLS / PERSONAL PROTECTION
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No.
Hexamethylene diisocyanate homopolymer
28182-81-2
Not Established
Not Established
Not Established
n-Butyl acetate
123-86-4
200 ppm STEL
150 ppm TWA
150 ppm TWA; 710 mg/m3 TWA
NIOSH: 150 ppm TWA; 710 mg/m3 TWA
200 ppm STEL; 950 mg/m3 STEL
Acetone
67-64-1
750 ppm STEL
500 ppm TWA
1000 ppm TWA; 2400 mg/m3 TWA
NIOSH: 250 ppm TWA; 590 mg/m3 TWA
Hexamethylene diisocyanate
822-06-0
0.005 ppm TWA
Not Established
NIOSH: 0.005 ppm TWA; 0.035 mg/m3 TWA
0.020 ppm Ceiling (10 min); 0.140 mg/m3 Ceiling (10 min)

Engineering Controls:  Avoid creating dust or mist. Local exhaust ventilation, process enclosures, or other engineering controls are required when handling or using this product to avoid over exposure. Use explosion-proof ventilation equipment. Do not use in closed or confined spaces. Keep all levels below exposure limits. Perform regular monitoring to ensure exposure limits are not exceeded.

Personal Protective Equipment (PPE):

Respiratory Protection - Do not breathe vapors. When concentrations exceed the established limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA) until vapors are exhausted. Observe OSHA standard 29 CFR 1910.134 and ANSI Z88.2 requirements whenever workplace conditions require a respirators use.

Hand Protection - Wear appropriate protective gloves and clothing to prevent skin exposure. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product.

Eye Protection - Use safety eyewear with splash guards or side shields. Use additional eye protection such as chemical safety goggles when the possibility for eye contact from splashing, spraying liquid, or airborne material 
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exists.

Skin Protection - Avoid contact with this product. Wear appropriate protective gloves and clothing to prevent skin exposure. Use proper glove and clothing removal techniques to avoid skin contact with this product. When handling large quantities, eye wash stations and deluge showers should be available.

Hygiene Measures:

General - When using do not eat or drink. Wash hands with soap and water before breaks and at the end of each workday.

Contaminated Equipment - Avoid contact with contaminated clothing and protective gear/equipment. Wash before reuse.

SECTION 9:     PHYSICAL AND CHEMICAL PROPERTIES

This mixture typically exhibits the following properties under normal circumstances:
Liquid Dispersion
Appearance
Organic Solvent
Odor
Liquid
Physical State
1.045
Specific Gravity (SG)
1.64
Lbs VOC/Gallon Less Water
-20°C, -4°F
Flash point:
196.02
g VOC/L Less Water
56 - 126°C
Boiling range:
SECTION 10:     STABILITY AND REACTIVITY

Product Stability (under normal conditions):
STABLE
Incompatible Materials:  Strong acids, strong bases, oxidizing agents
Avoid contact with Acids and Oxidizers
Hazardous Decomposition Products:  Carbon Dioxide (CO2), Carbon Monoxide (CO), Oxides of Nitrogen (NOx), dense black smoke
Hazardous polymerization will not occur.
SECTION 11:     TOXICOLOGICAL INFORMATION
Mixture Toxicity 
Inhalation Toxicity LC50: 1mg/L 
Note - Toxicological studies have not been performed on this mixture. The toxicological data listed is compiled using data from the components of the mixture. Refer to Section 2 of this SDS for GHS classification of acute and chronic effects of exposure.  
Principle Routes of Exposure:
Inhalation		Skin Contact		Eye Contact		Ingestion
May cause damage to the following organs:
Eyes		Kidneys		Liver		Lungs		Central Nervous System		Skin		Cardiovascular System		Respiratory System		
Carcinogenicity: The following chemicals comprise 0.1% or more of this mixture and are listed and/or classified as carcinogens or potential carcinogens by NTP, IARC, OSHA (mandatory listing) or ACGIH (optional listing):

Carcinogen Rating
CAS Number
Description
% Weight
None
None

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SECTION 12:     ECOLOGICAL INFORMATION

Bioaccumulative Potential:  No data available
Mobility in Soil:  No data available
Persistence and Degradability:  No data available

Component Ecotoxicity
n-Butyl acetate
96 Hr LC50 Lepomis macrochirus: 100 mg/L [static]; 96 Hr LC50 Pimephales promelas: 17 - 19 mg/L [flow-through]
72 Hr EC50 Desmodesmus subspicatus: 674.7 mg/L
Acetone
96 Hr LC50 Oncorhynchus mykiss: 4.74 - 6.33 mL/L; 96 Hr LC50 Pimephales promelas: 6210 - 8120 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: 8300 mg/L
48 Hr EC50 Daphnia magna: 10294 - 17704 mg/L [Static]; 48 Hr EC50 Daphnia magna: 12600 - 12700 mg/L
Hexamethylene diisocyanate
96 Hr LC50 Brachydanio rerio: 26.1 mg/L [static]
SECTION 13:     DISPOSAL CONSIDERATIONS

Do not discharge product into sewer system. Dispose of in a licensed facility. Waste management should be in full compliance with federal, state, and local laws.

The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance with 40 CFR 262, 263, 264, 268 and 270. Chemical additions, processing, or otherwise altering this material may make the waste management information presented in this SDS incomplete, inaccurate or otherwise inappropriate.
SECTION 14:     TRANSPORT INFORMATION

This material is classified for transport as follows:
UN Number
Proper Shipping Name
Agency
Packing Group
Hazard Class
U.S. DOT
Flammable Liquid, n.o.s (n-butyl acetate, acetone)
1993
3
III
SECTION 15:     REGULATORY INFORMATION

Additional regulatory listings where applicable

State of California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)  WARNING! This product contains the following substance(s) which are listed by the State of California as carcinogenic, or a reproductive toxin:
- None
Clean Air Act, Section 112, Hazardous Air Pollutants (HAPs) (see 40 CFR 61)  This product contains the following substance(s) which are listed as hazardous air pollutants (HAPs) per the Clean Air Act:
- None
Massachusetts Right To Know  This product contains the following toxic or hazardous substance(s) which appear on the Massachusetts Substance List:
123-86-4  n-Butyl acetate
67-64-1  Acetone
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New Jersey Worker and Community Right to Know Hazardous Substance List  The following substance(s) appear on the New Jersey Right to Know Hazardous Substance List:
123-86-4  n-Butyl acetate
67-64-1  Acetone
Commonwealth of Pennsylvania Worker and Community Right To Know Act  This product contains the following substance(s) which appear on the Pennsylvania Hazardous Substance List:
123-86-4  n-Butyl acetate
67-64-1  Acetone
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA)  This product contains a chemical or chemicals which are subject to the reporting requirements of the Act, and Title 40, of the Code of Federal Regulations, part 372:

- None
Canadian DSL All substances in this product except those listed below are listed or exempt from reporting:
28182-81-2  Hexamethylene diisocyanate homopolymer
123-86-4  n-Butyl acetate
67-64-1  Acetone
All Components Listed
Regulation
Country
Canada
Canadian NDSL
No
Australian
Australian Inventory of Chemical Substances
Yes
Japan
Existing and New Chemical Substances
Yes
China
Inventory of Existing Chemical Substances Produced or Imported in China
Yes
New Zealand
Inventory of Chemicals
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
Yes
Reach PBT/vPvB
No
TSCA Substance Control Act (TSCA)  All substances except those listed below appear in the Toxic Substances Control Act, Chemical Substance Inventory:

- None
SECTION 16:     OTHER INFORMATION

Disclaimer:  The Volatile Organic Compound (VOC) content reported herein, if any, is based on a material VOC calculation. Several methods are used for the calculation of VOC content, and the standards and requirements regarding VOC content vary by location or jurisdiction.

This document has been prepared using data from sources considered to be technically reliable and is believed to be correct as of the date hereof. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use, and to comply with all federal, state, provincial, and local laws and regulations.

Revision Notes:
Reviewer Revision  
Date Prepared:  6/21/2023
SDS for:  0365F201
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